Natural Gemstones
However certain rocks, (such as lapis lazuli) and organic materials (such as amber or jet) are not minerals, but are still used for jewelry, and are therefore often considered to be Natural Gemstones as well. Most gemstones are hard, but some soft minerals are used in jewelry because of their lustre or other physical properties that have aesthetic value. Rarity is another characteristic that lends value to a gemstone. Apart from jewelry, from earliest antiquity until the 19th century engraved gems and hardstone carvings such as cups were major luxury art forms; the carvings of Carl Faberg? were the last significant works in this tradition.
The traditional classification in the West, which goes back to the Ancient Greeks, begins with a distinction between precious and semi-precious stones; similar distinctions are made in other cultures. In modern usage the precious stones are diamond, ruby, sapphire and emerald, with all other gemstones being semi-precious. This distinction is unscientific and reflects the rarity of the respective stones in ancient times, as well as their quality: all are translucent with fine color in their purest forms, except for the colorless diamond, and very hard, with hardnesses of 8-10 on the Mohs scale. Other stones are classified by their color, translucency and hardness. The traditional distinction does not necessarily reflect modern values, for example, while garnets are relatively inexpensive, a green garnet called Tsavorite, can be far more valuable than a mid-quality emerald. Another unscientific term for semi-precious gemstones used in art history and archaeology is hardstone. Use of the terms ‘precious’ and ‘semi-precious’ in a commercial context is, arguably, misleading in that it deceptively implies certain stones are intrinsically more valuable than others, which is not the case.
In modern times Natural Gemstones are identified by gemologists, who describe gems and their characteristics using technical terminology specific to the field of gemology. The first characteristic a gemologist uses to identify a gemstone is its chemical composition. For example, diamonds are made of carbon (C) and rubies of aluminium oxide (Al2O3). Next, many gems are crystals which are classified by their crystal system such as cubic or trigonal or monoclinic. Another term used is habit, the form the gem is usually found in. For example diamonds, which have a cubic crystal system, are often found as octahedrons.
There are no universally accepted grading systems for any gemstone other than white (colorless) diamond. Diamonds are graded using a system developed by the Gemological Institute of America (GIA) in the early 1950s. Historically all gemstones were graded using the naked eye. The GIA system included a major innovation, the introduction of 10x magnification as the standard for grading clarity. Other <a href=” http://www.gemandgemstone.com “> Natural Gemstones </a> are still graded using the naked eye (assuming 20/20 vision).
A mnemonic device, the “four C’s” (color, cut, clarity and carat), has been introduced to help the consumer understand the factors used to grade a diamond.[8] With modification these categories can be useful in understanding the grading of all gemstones. The four criteria carry different weight depending upon whether they are applied to colored gemstones or to colorless diamond. In diamonds, cut is the primary determinant of value followed by clarity and color. Diamonds are meant to sparkle, to break down light into its constituent rainbow colors (dispersion) chop it up into bright little pieces (scintillation) and deliver it to the eye (brilliance). In its rough crystalline form, a diamond will do none of these things, it requires proper fashioning and this is called “cut”. In gemstones that have color, including colored diamonds, it is the purity and beauty of that color that is the primary determinant of quality.
Physical characteristics that make a colored stone valuable are color, clarity to a lesser extent (emeralds will always have a number of inclusions), cut, unusual optical phenomena within the stone such as color zoning, and asteria (star effects). The Greeks for example greatly valued asteria in gemstones, which were regarded as a powerful love charm, and Helen of Troy was known to have worn star-corundum.
Historically gemstones were classified into precious stones and semi-precious stones. Because such a definition can change over time and vary with culture, it has always been a difficult matter to determine what constitutes precious stones.
Diamond has a wide bandgap of 5.5 eV corresponding to the deep ultraviolet wavelength of 225 nanometers. This means pure diamond should transmit visible light and appear as a clear colorless crystal. Colors in diamond originate from lattice defects and impurities. The diamond crystal lattice is exceptionally strong and only atoms of nitrogen, boron and hydrogen can be introduced into diamond during the growth at significant concentrations (up to atomic percents). Transition metals Ni and Co, which are commonly used for growth of synthetic diamond by high-pressure high-temperature techniques, have been detected in diamond as individual atoms; the maximum concentration is 0.01% for Ni[24] and even much less for Co. Virtually any element can be introduced to diamond by ion implantation.
Nitrogen is by far the most common impurity found in gem diamonds. Nitrogen is responsible for the yellow and brown color in diamonds. Boron is responsible for the gray blue colors.Color in diamond has two additional sources: irradiation (usually by alpha particles), that causes the color in green diamonds; and plastic deformation of the diamond crystal lattice. Plastic deformation is the cause of color in some brown[26] and perhaps pink and red diamonds.In order of rarity, colorless diamond, by far the most common, is followed by yellow and brown, by far the most common colors, then by blue, green, black, translucent white, pink, violet, orange, purple, and the rarest, red. “Black”, or Carbonado, diamonds are not truly black, but rather contain numerous dark inclusions that give the gems their dark appearance. Colored diamonds contain impurities or structural defects that cause the coloration, while pure or nearly pure diamonds are transparent and colorless. Most diamond impurities replace a carbon atom in the crystal lattice, known as a carbon flaw. The most common impurity, nitrogen, causes a slight to intense yellow coloration depending upon the type and concentration of nitrogen present.[20] The Gemological Institute of America (GIA) classifies low saturation yellow and brown diamonds as diamonds in the normal color range, and applies a grading scale from “D” (colorless) to “Z” (light yellow). Diamonds of a different color, such as blue, are called fancy colored diamonds, and fall under a different grading scale.
